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Reductions with metal alkoxyaluminium hydrides : ウィキペディア英語版
Reductions with metal alkoxyaluminium hydrides
Reductions with metal alkoxyaluminium hydrides are chemical reactions that involve either the net hydrogenation of an unsaturated compound or the replacement of a reducible functional group with hydrogen by metal alkoxyaluminium hydride reagents.〔Málek, J. ''Org. React.'' 1985, ''34'', 1. 〕〔Málek, J. ''Org. React.'' 1988, ''36'', 249. 〕
==Introduction==
Sodium borohydride and lithium aluminium hydride are commonly used for the reduction of organic compounds.〔Brown, G. ''Org. React.'' 1951, ''6'', 469.〕〔Schenker, E. in ''Newer Methods of Preparative Organic Chemistry'', Vol. IV., W. Foerst, Ed., Academic Press, New York, 1968, pp. 163–335.〕 These two reagents are on the extremes of reactivity—whereas lithium aluminium hydride reacts with nearly all reducible functional groups, sodium borohydride reacts with a much more limited range of functional groups. Diminished or enhanced reactivity may be realized by the replacement of one or more of the hydrogens in these reagents with alkoxy groups.
Additionally, substitution of hydrogen for chiral alkoxy groups in these reagents enables asymmetric reductions.〔Itsuno, S. ''Org. React.'' 1998, ''52'', 395.〕 Although methods involving stoichiometric amounts of chiral metal hydrides have been supplanted in modern times by enantioselective catalytic reductions, they are of historical interest as early examples of stereoselective reactions.
The table below summarizes the reductions that may be carried out with a variety of metal aluminium hydrides and borohydrides. The symbol "+" indicates that reduction does occur, "-" indicates that reduction does not occur, "±" indicates that reduction depends on the structure of the substrate, and "0" indicates a lack of literature information.
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